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CasNo: 316-61-0
MF: C12H10FN
A compound of Formula I wherein X1 and X...
In this study, a structure-activity rela...
A traceless directing group assisted Co-...
A facile and efficient approach is devel...
fluorobenzene
phenylhydrazine
4'-fluoro-biphenyl-2-ylamine
N-(4-fluorophenyl)aniline
2'-fluoro-[1,1'-biphenyl]-2-amine
| Conditions | Yield |
|---|---|
|
With
aluminium trichloride;
at 20 ℃;
for 2.5h;
|
30% 9% 14% |
2-iodophenylamine
o-fluorophenylboronic acid
2'-fluoro-[1,1'-biphenyl]-2-amine
| Conditions | Yield |
|---|---|
|
With
dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2; potassium carbonate;
In
1,4-dioxane; water;
at 90 ℃;
for 2h;
|
66% |
|
With
palladium diacetate; potassium carbonate;
In
water; acetone;
at 65 ℃;
Sealed tube;
Inert atmosphere;
|
|
|
With
(1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; tetrabutylammomium bromide; potassium carbonate;
In
1,4-dioxane; water;
at 130 ℃;
for 1h;
Microwave irradiation;
|
|
|
With
potassium phosphate; tetrakis(triphenylphosphine) palladium(0);
In
ethanol;
for 24h;
Reflux;
Inert atmosphere;
|
2-fluoro-2′-nitrobiphenyl
fluorobenzene
phenylhydrazine
1-Fluoro-2-iodobenzene
N-benzoyl-N'-(2'-fluoro-2-biphenylyl)thiourea